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What are the principles of statistical mechanics?

Statistical mechanics is a mathematical framework that uses probability theory and statistical methods to explain the macroscopic properties of matter in aggregate. It arose from classical thermodynamics to clarify macroscopic parameters like temperature, pressure, and heat capacity in terms of microscopic atomic motion. Josiah Willard Gibbs published a foundational treatise on this subject in 1902 titled Elementary Principles in Statistical Mechanics.

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